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electrophilic amination
Electrophilic amination is a chemical process involving the formation of a carbon–nitrogen bond through the reaction of a nucleophilic carbanion with an electrophilic source of nitrogen.〔Ciganek, E. ''Org. React.'' 2008, ''72'', 1–86. 〕
==Introduction==
Electrophilic amination reactions can be classified as either additions or substitutions. Although the resulting product is not always an amine, these reactions are unified by the formation of a carbon–nitrogen bond and the use of an electrophilic aminating agent. A wide variety of electrophiles have been used; for substitutions, these are most commonly amines substituted with electron-withdrawing groups: chloramines, hydroxylamines, hydrazines, and oxaziridines, for instance. Addition reactions have employed imines, oximes, azides, azo compounds, and others.
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